Estimating percentiles in air dispersion modelling

I have recently been providing advice to STIMBR (Stakeholders in Methyl Bromide Reduction) on the estimation of percentiles when modelling the dispersion of chemicals in the atmosphere. It was interesting to see just how unreliably the highest upper percentiles of a skewed distribution are estimated, even from a very large sample. This has implications for the use of such percentiles in setting environmental health regulations.

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